Cat.NO.:A428706 Purity:95%
Product Details of [ 100943-46-2 ]
| CAS No. : | 100943-46-2 |
| Formula : |
C11H16OS |
| M.W : |
196.31
|
| SMILES Code : | O=CC1=CC=C(CCCCCC)S1 |
| MDL No. : | MFCD11044868 |
| InChI Key : | VWCAHBARARIQLV-UHFFFAOYSA-N |
| Pubchem ID : | 11469651 |
Safety of [ 100943-46-2 ]
| GHS Pictogram: |   |
| Signal Word: | Danger |
| Hazard Statements: | H302-H413-H334 |
| Precautionary Statements: | P261-P264-P270-P273-P285-P301+P312-P304+P341-P330-P342+P311-P501 |
| Class: | 6.1 |
| UN#: | 2810 |
| Packing Group: | Ⅲ |
Application In Synthesis of [ 100943-46-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 100943-46-2 ]
[ 100943-46-2 ] Synthesis Path-Downstream 1~2
- 1
[ 100943-46-2 ]
[ 27063-90-7 ]
[ 847257-97-0 ]
References: [1]Tetrahedron Letters,2003,vol. 44,p. 5879 – 5882.
- 2
[ 109-97-7 ]- [ 100943-46-2 ]
[ 67808-64-4 ]- 5-(5-methoxycarbonylthiophen-2-yl)-10,15,20-tri(5-hexylthiophen-2-yl)porphyrin [ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
|---|---|---|
| 1.43 g | In a reaction vessel,Pyrrole (1.26 g),2-formyl-5-hexylthiophene (2.77 g),<strong>[67808-64-4]5-formylthiophene-2-carboxylic acid methyl ester</strong> (0.80 g),Chloroform (700 mL)And ethanol (3 mL) were added,It was cooled to about 10 ° C.There,Boron trifluoride (0.67 g) was added dropwise,The mixture was stirred for 2 hours.To this solution,2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (3.20 g) was added,And the mixture was further stirred for 1 hour.The reaction solution was passed through Celite and silica gel,The filtrate was concentrated to obtain a crude product.This was developed and separated by a silica gel column (chloroform / hexane = 3/2 ? 5/1)The product (5-(5-methoxycarbonylthiophen-2-yl)-10,15,20-tri(5-hexylthiophene-2-yl)porphyrin, 1.43 g) was obtained. |
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